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New Mexico State University

Innovative Sulfate Removal from Groundwater Associated with Sulfide Mineralization

10/13/08 inconstancy found change is noted below - pH is not acidic rather pH averages 7.9

11/20/08 Sponsor has opted to provide more specific water sample data, link below

    Research, prioritize, develop and demonstrate an innovative and cost effective technology that employs or replaces conventional water treatment methods for the removal of sulfate from groundwater and/or surface water primarily derived from sulfide mineralization.

Table of Contents

Background Problem Statement
Design Considerations Evaluation Criteria
Bench-Scale Demonstration Written Report Requirements
For More Information  

Background

    Mineral recovery from ore deposits associated with sulfide mineralization can result in metal, sulfate and total dissolved solids (TDS) loading to groundwater and/or surface water.  One of the challenges in site management and closure of a sulfide mineralized ore deposit is the treatment of metals followed by the treatment for sulfate removal to meet surface or groundwater standards.  Sulfate removal is more challenging when found in a sodium (Na) environment versus a calcium (Ca) environment, both of which can be associated with sulfide mineralization.


Problem Statement

    Following completion of the research and prioritization phase of the task, develop and demonstrate as cost effective process that addresses the removal of sulfate to meet federal or state surface water standards and state groundwater standards.  Not all states have primacy over the Environmental Protection Agency (EPA) under the Clean Water Act.  In addition, most all states regulate groundwater within their state boundaries.  Assume that the treatment of sulfate and metals must meet the State of New Mexico standards.


Design Considerations

    The approach and technology chosen should:

·     be able to treat metals and reduce sulfate from the source of affected water sufficiently to meet applicable regulatory standards;

·     understand the requirements for any by-product waste disposal and determine the optimum method;

·     be efficient and cost effective;

·     establish the long-term operating and maintenance costs for the recommended technology;

·     meet all state and/or federal regulatory standards; and

·     be adaptable to different sized influent streams that could range from several hundreds of gallons to several thousands of gallons.


Evaluation Criteria

    Each team is advised to read the Participation Guide for a comprehensive understanding or the contest evaluation criteria.  Upon your registration, WERC will provide you with a copy of the Public Involvement Plan and Participation Guide.  Additionally, your proposed design will be evaluated on issues identified in the problem statement as well as the others listed below:

            ·        Understanding of present water treatment practices;

·       Practicality of proposed method;

·       Magnitude of potential cost reduction compared with current treatment practices;

·       Long-term performance of system and operations and maintenance requirements;

·       Justification for cost reduction predictions;

·       System reliability;

·       Novelty of proposed methods – dilution by use of clean water is not an acceptable method;

·       Originality of bench-scale demonstration; and

·       Potential uses of treated water and optimum method for management of potential waste generated.


Bench-Scale Demonstration

    During the contest, WERC will provide up to 5 gallons (should you need more for your process to operate during the bench scale test you must be communicate with WERC at least three weeks before the contest at New Mexico State University) of a sample consistent with typical sulfide mineralized solution from a sulfide ore body containing various amounts of metals, TDS and sulfate with a pH averaging 7.9.  Variability in samples received at different times in the process should be anticipated. A water sample from the site yielded the following results:

   

Additional information provided by sponsor on 11/20/08: Spreadsheet


Written Report Requirements

    The written report is the best means to demonstrate your team’s insight into the problem.  The report should discuss other technologies considered but not pursued and why and to give the reader full understanding of the magnitude of your team’s involvement with the problem details.  The report will be evaluated for clarity, logic and coherence.  Standards appropriate for the publication in technical journals apply.

    In addition to the listed requirements, the following must be discussed in your report to WERC management:

            ·       Describe research approach, process steps, evaluation criteria and screening protocol in detail;

·       Present cost/benefit analysis, NPV results, operations and maintenance costs for long-term treatment requirements;

·       Provide schematics of process flow diagram, pictures or other presentation material to clearly explain your process;

·       Address any safety issues or concerns with your process and how they will be managed;

·       Discuss the timeline for system revaluation for pilot scale verification of your process to confirm its ability to be placed into full     

          scale production and challenges that need to be verified and the pilot scale stage; and

·       Address regulatory requirements and waste generation management if applicable.



For More Information

Contact:
Barbara Valdez, Program Facilitator
(575) 646-7821
(800) 523-5996